Piezoelectric bulk wave device, and method of manufacturing the piezoelectric bulk wave device

ABSTRACT

A piezoelectric bulk wave device that includes a piezoelectric thin plate that is made of LiTaO 3 , and first and second electrodes that are provided in contact with the piezoelectric thin plate. The piezoelectric bulk wave device utilizes the thickness shear mode of the piezoelectric thin plate made of LiTaO 3 , and of the Euler Angles (φ, θ, φ) of LiTaO 3 , φ is 0°, and θ is in the range of not less than 54° and not more than 107°.

CROSS REFERENCE TO RELATED APPLICATIONS

The present application is a continuation of International application No. PCT/JP2012/071639, filed Aug. 28, 2012, which claims priority to Japanese Patent Application No. 2011-190344, filed Sep. 1, 2011, the entire contents of each of which are incorporated herein by reference.

FIELD OF THE INVENTION

The present invention relates to a piezoelectric bulk wave device using LiTaO₃, and a method of manufacturing the piezoelectric bulk wave device. More specifically, the present invention relates to a piezoelectric bulk wave device that utilizes a bulk wave of thickness shear mode as a bulk wave, and a method of manufacturing the piezoelectric bulk wave device.

BACKGROUND OF THE INVENTION

In related art, piezoelectric thin film devices are used for oscillators, filters, and the like. For example, a piezoelectric thin film device illustrated in FIG. 16 is disclosed in Patent Document 1 mentioned below. A piezoelectric thin film device 1001 has a piezoelectric thin film 1002. It is described in Patent Document 1 that the piezoelectric thin film 1002 is desirably made of piezoelectric monocrystal, such as quartz crystal, LiTaO₃, or LiNbO₃. Electrodes 1003 and 1004 are formed on the upper surface of the piezoelectric thin film 1002. Electrodes 1005 to 1007 are formed on the lower surface of the piezoelectric thin film 1002. By using the electrodes 1003 to 1007, four piezoelectric thin film resonators that utilize thickness shear mode are formed in the piezoelectric thin film device 1001.

-   Patent Document 1: Japanese Unexamined Patent Application     Publication No. 2007-228356

SUMMARY OF THE INVENTION

As described in Patent Document 1, in related art, piezoelectric thin film devices using the thickness shear mode of LiTaO₃ are known. However, in a case where thickness shear vibration mode is utilized by using a piezoelectric thin film made of LiTaO₃, it is difficult to make the electromechanical coupling coefficient k² of the thickness shear mode sufficiently high. For this reason, it is difficult to achieve a wider frequency band or increase the adjustable range of band width.

It is an object of the present invention to provide a piezoelectric bulk wave device that utilizes the thickness shear mode of LiTaO₃, and also have a high electromechanical coupling coefficient k², and a method of manufacturing the piezoelectric bulk wave device.

A piezoelectric bulk wave device according to the present invention utilizes the thickness shear mode of a piezoelectric thin plate made of LiTaO₃. The piezoelectric bulk wave device according to the present invention has a piezoelectric thin plate that is made of LiTaO₃, and first and second electrodes that are provided in contact with the piezoelectric thin plate. According to the present invention, of Euler Angles (φ, θ, φ) of LiTaO₃, φ is 0°, and θ is in a range of not less than 54° and not more than 107°. According to the present invention, preferably, the θ of the Euler Angles is in a range of 55° to 88°, in which case the electromechanical coupling coefficient of thickness longitudinal vibration which is a spurious mode can be made sufficiently small.

According to the present invention, more preferably, the θ of the Euler Angles is in a range of 62° to 87°. In this case, the absolute value of the temperature coefficient of frequency TCF can be made small.

A method of manufacturing a piezoelectric bulk wave device according to the present invention is a method of manufacturing a piezoelectric bulk wave device that utilizes a thickness shear mode of a piezoelectric thin plate made of LiTaO₃, and includes the steps of preparing a piezoelectric thin plate that has Euler Angles (φ, θ, φ), of which φ is 0° and θ is in a range of not less than 54° and not more than 107°, forming a first electrode in contact with the piezoelectric thin plate, and forming a second electrode in contact with the piezoelectric thin plate.

In a specific aspect of the method of manufacturing a piezoelectric bulk wave device according to the present invention, the step of preparing the piezoelectric thin plate includes the steps of implanting ions from one side of a piezoelectric substrate made of LiTaO₃ to form a high concentration ion-implanted portion on the one side, the high concentration ion-implanted portion being a portion of highest implanted-ion concentration, joining a support substrate to the one side of the piezoelectric substrate, and separating the piezoelectric substrate at the high concentration ion-implanted portion while heating the piezoelectric substrate, into a piezoelectric thin plate that extends from the one side of the piezoelectric substrate to the high concentration ion-implanted portion, and a remaining piezoelectric substrate portion.

In this case, the position of the high concentration ion-implanted portion can be easily controlled by selecting the above-mentioned ion implantation conditions. Generally, an ion beam from an ion implantation device is linearly applied to the substrate with uniform intensity, and the ion beam is applied a number of times at substantially the same irradiation angle to the same location while scanning the entire substrate. Accordingly, in comparison to thickness variations due to film deposition methods such as sputtering, CVD, and evaporation, by using ion implantation, the position of the high concentration ion-implanted portion becomes uniform over the entire substrate surface, leading to smaller variations in depth. Therefore, it is possible to easily obtain a piezoelectric thin plate with an accurate thickness over the entire substrate surface.

In another specific aspect of the method of manufacturing a piezoelectric bulk wave device according to the present invention, the step of preparing the piezoelectric thin plate includes the steps of implanting ions from one side of a piezoelectric substrate made of LiTaO₃ to form a high concentration ion-implanted portion on the one side, the high concentration ion-implanted portion being a portion of highest implanted-ion concentration, bonding a temporary support member onto the one side of the piezoelectric substrate, and separating the piezoelectric substrate at the high concentration ion-implanted portion while heating the piezoelectric substrate bonded on the temporary support member, into a piezoelectric thin plate that extends from the one side of the piezoelectric substrate to the high concentration ion-implanted portion, and a remaining piezoelectric substrate portion, and the method includes the step of detaching the temporary support member from the piezoelectric thin plate.

In this case, it is possible to reduce the possibility of a defect occurring in the piezoelectric thin plate due to thermal stress exerted when separating the piezoelectric thin plate.

In still another specific aspect of the method of manufacturing a piezoelectric bulk wave device according to the present invention, prior to detaching the temporary support member from the piezoelectric thin plate, the steps of forming a first electrode on the piezoelectric thin plate, forming a dummy layer so as to cover the first electrode, and laminating a support substrate on the dummy layer are performed. In addition, the method further includes the steps of, after detaching the temporary support member from the piezoelectric thin plate, forming a second electrode on another side of the piezoelectric thin plate which is exposed by the detaching of the temporary support member, and causing the dummy layer to disappear. In this case, in accordance with the present invention, it is possible to provide a piezoelectric bulk wave device having a structure in which a vibrating part having the first and second electrodes formed on the top and the bottom of the piezoelectric thin plate is made afloat from the support substrate.

In the piezoelectric bulk wave device according to the present invention, for the piezoelectric thin plate made of LiTaO₃, φ is 0° and θ is in the range of not less than 54° and not more than 107°, and thus the electromechanical coupling coefficient k² of the thickness shear more can be increased. Therefore, it is possible to provide a piezoelectric bulk wave device that has a wide band width, or a piezoelectric bulk wave device that provides a wide adjustable range of band width.

BRIEF DESCRIPTION OF THE DRAWINGS

FIGS. 1( a) and 1(b) are an elevational cross-sectional view and a plan view, respectively, of a piezoelectric bulk wave device according to an embodiment of the present invention.

FIG. 2 illustrates the relationship between the Euler Angles θ of LiTaO₃, and the resonant frequency Fr and anti-resonant frequency Fa of thickness shear mode.

FIG. 3 illustrates the relationship between the Euler Angles θ of LiTaO₃, and the electromechanical coupling coefficient k² of thickness shear mode.

FIG. 4 illustrates the relationship between the Euler Angles θ of LiTaO₃, and the temperature coefficient of frequency TCF of thickness shear mode.

FIG. 5 illustrates the relationship between the Euler Angles θ of LiTaO₃, and the electromechanical coupling coefficient ksp² of thickness longitudinal vibration mode that is spurious.

FIG. 6 illustrates the relationship between the Euler Angles θ of LiTaO₃, and the resonant frequency Fr and anti-resonant frequency Fa of thickness longitudinal vibration.

FIG. 7 illustrates the relationship between the Euler Angles θ of LiTaO₃, and the electromechanical coupling coefficient k² of thickness longitudinal vibration.

FIG. 8 illustrates the relationship between the Euler Angles θ of LiTaO₃, and temperature coefficient of frequency TCF.

FIG. 9 illustrates the relationship between Euler Angles θ and temperature coefficient of frequency TCF in thickness shear vibration mode, in a case where LiNbO₃ is used.

FIG. 10 illustrates the impedance characteristics and phase characteristics of a piezoelectric bulk wave device according to a first embodiment.

FIG. 11 is an impedance Smith chart of the piezoelectric bulk wave device according to the first embodiment.

FIGS. 12( a) to 12(d) are schematic elevational cross-sectional views for explaining a method of manufacturing a piezoelectric bulk wave device according to an embodiment of the present invention.

FIGS. 13( a) to 13(c) are schematic elevational cross-sectional views for explaining a method of manufacturing a piezoelectric bulk wave device according to an embodiment of the present invention.

FIGS. 14( a) to 14(c) are schematic elevational cross-sectional views for explaining a method of manufacturing a piezoelectric bulk wave device according to an embodiment of the present invention.

FIGS. 15( a) to 15(c) are schematic elevational cross-sectional views for explaining a method of manufacturing a piezoelectric bulk wave device according to an embodiment of the present invention.

FIG. 16 is a schematic cross-sectional view illustrating an example of a piezoelectric thin film device according to related art.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Hereinafter, the present invention will be explained by way of specific embodiments of the present invention with reference to the drawings.

FIGS. 1( a) and 1(b) are a schematic elevational cross-sectional view and a plan view, respectively, of a piezoelectric bulk wave device according to an embodiment of the present invention.

A piezoelectric bulk wave device 1 according to this embodiment has a support substrate 2. The support substrate 2 is formed by a suitable insulating body or piezoelectric body. In this embodiment, the support substrate 2 is formed by alumina.

An insulating layer 3 is formed on the support substrate 2. While the insulating layer 3 is made of silicon oxide in this embodiment, the insulating layer 3 may be made of a suitable insulating material such as LiTaO₃, LiNbO₃, sapphire, or glass. Alumina, glass, and LiNbO₃ are preferred because these materials are inexpensive in comparison to LiTaO₃ and sapphire, and easy to manufacture. A recess 3 a is formed on the upper surface of the insulating layer 3. A piezoelectric thin plate vibrating part 4 is disposed above the portion where the recess 3 a is provided. The piezoelectric thin plate vibrating part 4 has a piezoelectric thin plate 5, a first electrode 6 formed on the upper surface of the piezoelectric thin plate 5, and a second electrode 7 formed on the lower surface of the piezoelectric thin plate 5.

The piezoelectric thin plate 5 is made of LiTaO₃. The piezoelectric thin plate 5 refers to a thin monocrystal piezoelectric body with a thickness of, for example, not more than 2 μm. According to a manufacturing method described later, such a piezoelectric thin plate made of LiTaO₃ having a small thickness can be obtained with high accuracy by using an ion implantation-splitting method.

The first electrode 6 and the second electrode 7 are each made of a suitable metal or an alloy mainly including the metal. Such a metal or alloy may be selected as appropriate depending on the physical value required. For example, in a case where heat resistance is required, a high-melting metal such as W, Mo, Ta, or Hf may be used. Alternatively, Cu or Al which has a low electrical resistance may be used. Further, Pt, which is unlikely to cause thermal diffusion, may be used. Further, Ti, Ni, or the like that provides good adhesion with LiTaO₃ may be used. The first and second electrodes 6 and 7 may be each formed by a laminated metal film including a plurality of metal films laminated.

The method of forming the first and second electrodes 6 and 7 is not particularly limited, either. A suitable method such as electron-beam evaporation, chemical vapor deposition, sputtering, or CVD may be used.

FIG. 1( a) corresponds to the cross-section of the portion taken along the line A-A in FIG. 1( b). The piezoelectric thin plate 5 has slits 5 a and 5 b on opposite sides of a direction along the line A-A of the recess 3 a. Accordingly, as illustrated in FIG. 1( a), the piezoelectric thin plate vibrating part 4 is made afloat above the recess 3 a. On the outer side portion of the slit 5 a, a line electrode 8 is formed on the insulating layer 3. The line electrode 8 is connected to the second electrode 7 in a portion not illustrated in the drawing. In addition, a line electrode 9 is formed on the outer side portion of the slit 5 b. The line electrode 9 is formed on the piezoelectric thin plate 5, and is electrically connected to the first electrode 6 in a portion not illustrated in the drawing. The line electrodes 8 and 9 are each made of a suitable conductive material. As such a conductive material, Cu, Al, an alloy of these materials, or the like may be used.

A gold bump 10 is provided on the line electrode 9. In addition, a via-hole electrode 11 is provided in the piezoelectric thin plate 5 so as to be electrically connected to the line electrode 8. A gold bump 12 is joined to the upper end of the via-hole electrode 11. Accordingly, the piezoelectric thin plate vibrating part 4 can be vibrated by application of an alternating electric field from each of the gold bumps 10 and 12. In addition, because the line electrode 8 that transmits a principal electric signal is spaced apart from the joint interface between the insulating layer 3 and the support substrate 2, the line electrode 8 is less prone to the influence of semiconductor-like resistance degradation due to diffusion or non-uniformity at the joint interface or the skin effect. Therefore, principal electrical signal can be transmitted with low loss.

A characteristic feature of the piezoelectric bulk wave device 1 according to this embodiment resides in that the thickness shear vibration mode of the piezoelectric thin plate 5 made of LiTaO₃ is utilized for the piezoelectric thin plate vibrating part 4, and of the Euler Angles (φ, θ, φ) of LiTaO₃, φ is 0°, and θ is in the range of not less than 54° and not more than 107°. As a result, good resonance characteristics utilizing thickness shear vibration mode can be obtained. This will be described in more detail below.

By the finite element method, a bulk wave oscillator that utilizes thickness shear vibration mode and thickness longitudinal vibration mode using LiTaO₃ was analyzed. The thickness of LiTaO₃ was set to 1000 nm. A structure in which electrodes having a thickness of 100 nm and made of Al are formed on the top and the bottom of this LiTaO₃ was used as a model. The area over which the upper and lower electrodes overlap was set to 2000 μm².

Of the Euler Angles (0°, θ, 0°) of LiTaO₃, θ was varied, and the states of the thickness shear vibration mode and thickness longitudinal vibration mode were analyzed. The results are illustrated in FIGS. 2 to 8.

FIG. 2 illustrates the relationship between θ of the Euler Angles, and the resonant frequency Fr and anti-resonant frequency Fa of the thickness shear vibration mode. In FIG. 2, the solid line indicates resonant frequency, and the broken line indicates anti-resonant frequency. FIG. 3 illustrates the relationship between θ of the Euler Angles, and the electromechanical coupling coefficient k² of the thickness shear vibration mode. As is apparent from FIG. 3, the electromechanical coupling coefficient k² of the thickness shear vibration mode used takes the maximum value of 14.3% when θ is in the vicinity of 80°. In this regard, when θ is in the range of not less than 54° and not more than 107°, the resulting electromechanical coupling coefficient k² exceeds 5%, thus providing an electromechanical coupling coefficient required for producing the band width of a filter for portable terminal applications. Further, when θ is in the range of not less than 63° and not more than 97°, the resulting electromechanical coupling coefficient k² still keeps a large value of 9.5% or more, which is two-thirds of the above-mentioned maximum value. The electromechanical coupling coefficient k² is proportional to the band width of a filter. Accordingly, it is appreciated that by setting θ of the Euler Angles to be not less than 54° and not more than 107°, the electromechanical coupling coefficient k² can be increased, and a bulk wave filter that covers a wide frequency band can be provided.

Therefore, it is appreciated that according to this embodiment, a bulk wave device that covers a wide frequency band can be provided by setting θ of the Euler Angles to be not less than 54° and not more than 107°. That said, depending on the intended application, it is not always desirable to make the band width as large as possible. However, the band width can be narrowed by adding an electrostatic capacity in parallel to or in series with a bulk wave resonator. Accordingly, in a case where the electromechanical coupling coefficient k² is large, the freedom of design can be increased. Therefore, according to this embodiment, because θ of the Euler Angles is not less than 54° and not more than 107°, and the electromechanical coupling coefficient k² is large, bulk wave devices for various band widths can be easily provided.

As is apparent from FIG. 5, the electromechanical coupling coefficient k² of the thickness longitudinal vibration mode that is spurious becomes substantially zero when θ is 73°. This also agrees with the results illustrated in FIG. 7. That is, FIGS. 6 to 8 explain variation of the thickness longitudinal vibration mode that is spurious due to θ of the Euler Angles. FIG. 6 illustrates the relationship between θ of the Euler Angles, and the resonant frequency Fr and anti-resonant frequency Fa of thickness longitudinal vibration. In FIG. 6, the solid line indicates the results on resonant frequency, and the broken line indicates the results on anti-resonant frequency. FIG. 7 illustrates the relationship between θ of the Euler Angles and the electromechanical coupling coefficient k² of thickness longitudinal vibration. FIG. 8 illustrates the relationship between θ of the Euler Angles and temperature coefficient of frequency TCF. As is also apparent from FIGS. 6 to 8, when θ of the Euler Angles is 73°, the electromechanical coupling coefficient k² of the thickness longitudinal vibration mode that is spurious becomes substantially zero, and when θ is in the range of not less than 55° and not more than 85°, as is apparent from FIG. 5, the electromechanical coupling coefficient k² of the thickness longitudinal vibration mode that is spurious has a very small value of 1.5% or less.

Therefore, preferably, it is desirable to set θ of the Euler Angles to be in the range of not less than 55° and not more than 85°. As a result, the response of the thickness longitudinal vibration mode that is spurious can be made small. Therefore, in a case where a piezoelectric bulk wave device is configured in accordance with the above-mentioned embodiment, the attenuation characteristics in the stop band of the filter can be improved.

As is apparent from FIG. 4, the temperature coefficient of frequency TCF of the thickness shear vibration mode is small at 21.4 ppm/° C. when θ=75°. Further, when θ is in the range of not less than 62° and not more than 87°, the TCF is small at 30 ppm/° C. or less. Therefore, preferably, it is desirable to set θ to be within the range of not less than 62° and not more than 87°. As a result, the passband or stopband of the filter in the piezoelectric bulk wave device 1 is unlikely to shift with a change in environmental temperature. That is, it is possible to provide the piezoelectric bulk wave device 1 that is stable against fluctuations in frequency.

FIG. 9 illustrates the relationship between the Euler Angle θ and temperature coefficient of frequency TCF in the thickness shear vibration mode in a case where LiNbO₃ is used. For LiNbO₃, as in the case of LiTaO₃, the TCF in the vicinity of θ=73° at which the electrochemical coupling coefficient k² of the thickness longitudinal vibration mode that is spurious becomes small is checked, and the result indicates that the TCF is 96 ppm/C.°, which is nearly five times as large as the TCF of 21.4 ppm/C.° in the case of LiTaO₃. Therefore, it can be said that it is preferable to use LiTaO₃ as a piezoelectric thin plate.

In FIGS. 2 to 8, a structure in which electrodes made of Al are formed on the upper and lower surfaces of LiTaO₃ was examined as a model. However, it has been confirmed that even if the electrode material is changed to another metal, although the absolute value of the electromechanical coupling coefficient k² may change, setting θ of the Euler Angles within the same range as mentioned above can increase the electromechanical coupling coefficient k², and further, setting θ within the above-mentioned desirable range can reduce spurious, or can make the absolute value of TCF smaller.

FIGS. 10 and 11 are an illustration of the impedance characteristics and phase characteristics, and an impedance Smith chart, respectively, of the piezoelectric bulk wave device 1 according to this embodiment mentioned above. In this example, the piezoelectric thin plate 5 made of LiTaO₃ has Euler Angles of (0°, 85°, 0°), and a thickness of 0.85 μm. Further, the first electrode 6 and the second electrode 7 are each made of aluminum, and have a film thickness of 75 nm. Further, a layer of Ti with a small thickness of 10 nm is arranged as an adhesion layer between aluminum and LiTaO₃. As is apparent from FIGS. 10 and 11, with a resonant frequency of 1990 MHz, and an anti-resonant frequency of 2196 MHz, resonant characteristics with a wide band width of 10.3% are obtained.

Next, an example of a method of manufacturing the piezoelectric bulk wave device 1 will be described with reference to FIGS. 12( a) to 15(c).

As illustrated in FIG. 12( a), a piezoelectric substrate 5A made of LiTaO₃ is prepared. Hydrogen ions are implanted as indicated by arrows from one side of the piezoelectric substrate 5A. Ions to be implanted are not limited to hydrogen but helium or the like may be used. Although the energy at which ions are implanted is not particularly limited, this embodiment adopts the following conditions: a dose of 8×10¹⁷ atoms/cm at 150 KeV. The above-mentioned ion implantation conditions may be selected in accordance with the target thickness of the piezoelectric thin plate. That is, the position of the high concentration ion-implanted portion can be controlled by selecting the above-mentioned ion implantation conditions.

Upon implanting ions, an ion concentration distribution occurs in the thickness direction within the piezoelectric substrate 5A. The portion of the highest ion concentration is indicated by a broken line in FIG. 12. In a high concentration ion-implanted portion 5 x representing the portion of the highest ion concentration indicated by the broken line, the piezoelectric substrate 5A can be easily separated owing to stress when heated. This method of separation using the high concentration ion-implanted portion 5 x is disclosed in Japanese Unexamined Patent Application Publication (Translation of PCT Application) No. 2002-534886.

Next, as illustrated in FIG. 12( b), a temporary joining layer 21 is formed on the side of the piezoelectric substrate 5A from which ions have been implanted. The temporary joining layer 21 is provided for the purpose of joining a temporary support member 22 described later, and also protecting the piezoelectric thin plate 5 that is finally obtained. The temporary joining layer 21 is made of a material that is removed by an etching step described later. That is, the temporary joining layer 21 is made of a suitable material that is removed by etching, and does not damage the piezoelectric thin plate 5 at the time of etching. As such a material for forming the temporary joining layer 21, a suitable material such as an inorganic material or an organic material may be used. As the inorganic material, an insulating inorganic material such as ZnO, SiO₂, or AlN, or a metal material such as Cu, Al, or Ti may be given as an example, and as the organic material, a material such as polyimide may be given as an example. The temporary joining layer 21 may be a laminate of a plurality of films made of such a material. In this embodiment, the temporary joining layer 21 is made of SiO₂.

The temporary support member 22 is laminated and bonded onto the temporary joining layer 21 as illustrated in FIG. 12( c). The temporary support member 22 may be made of a suitable rigid material. As such a material, a suitable material such as insulating ceramic or piezoelectric ceramic may be used. In this regard, the temporary support member is made of such a material that hardly any thermal stress is exerted at the interface with the piezoelectric substrate, or such a material that when the support substrate and the piezoelectric substrate are joined, the thermal stress exerted at the interface between the temporary support member and the piezoelectric substrate is smaller than the thermal stress exerted at the interface between the support substrate and the piezoelectric substrate. Consequently, in comparison to related art, it is possible to reduce the possibility of a defect occurring in the piezoelectric thin plate due to thermal stress exerted when separating the piezoelectric thin plate. Further, because the support substrate is formed on the piezoelectric thin plate after heating is performed to split the piezoelectric thin plate, as the material for forming the support substrate, a material with any coefficient of linear expansion may be used without considering the thermal stress that is exerted at the interface between the support substrate and the piezoelectric thin plate.

For this reason, the selectively of the combination of the material for forming the piezoelectric thin plate and the material for forming the support substrate can be increased. For example, for devices used for filter applications, it is possible to improve the temperature-frequency characteristics of the filter by making the coefficient of linear expansion of the material of the support substrate significantly lower than the coefficient of linear expansion of the piezoelectric thin plate. In addition, by selecting a material with high thermal conductivity for the support substrate, it is possible to improve heat radiation property and electric power handling capability. Therefore, by selecting an inexpensive material, it is possible to reduce the manufacturing cost of the resulting device.

Next, heating is applied to facilitate splitting of the piezoelectric substrate 5A at the high concentration ion-implanted portion 5 x. As for the heating temperature for facilitating splitting of the piezoelectric substrate 5A at the high concentration ion-implanted portion 5 x, in this embodiment, heating is performed by keeping the temperature at about 250° C. to 400° C.

An external force is applied in that state to split the piezoelectric substrate 5A. That is, at the high concentration ion-implanted portion 5 x, the piezoelectric thin plate 5 and the remaining piezoelectric substrate portion are separated so as to leave the piezoelectric thin plate 5 illustrated in FIG. 6( d), and then the remaining piezoelectric substrate portion is removed.

After splitting the piezoelectric substrate 5A by heating, it is desirable to apply heating treatment for recovering piezoelectricity as appropriate. As such heating treatment, heating may be maintained for about three hours at a temperature of 400° C. to 500° C.

The heating temperature required for recovering the piezoelectricity mentioned above may be set higher than the heating temperature in the splitting mentioned above. As a result, piezoelectricity can be effectively recovered.

Next, as illustrated in FIG. 13( a), an electrode structure including the second electrode 7 and the line electrode 8 is formed on the piezoelectric thin plate 5 by photolithography. Further, a protective film 8 a is formed so as to cover the line electrode 8.

Next, as illustrated in FIG. 13( b), a dummy layer 23 is formed so as to cover the second electrode 7. The dummy layer 23 is made of a material that can be removed by etching. As such a material for forming the dummy layer, an insulating film of SiO₂, ZnO, phospho-silicate glass (PSG), or the like, various kinds of organic films, a metal with high selectivity of dissolution in the lower electrode or a passivation film covering the lower electrode, or the like may be used. In this embodiment, Cu is used. As an etchant used for the above-mentioned etching, a suitable material that allows only the dummy layer to be removed by etching without etching the second electrode 7 may be used.

As illustrated in FIG. 13( c), the insulating layer 3 is formed on the entire surface so as to cover the dummy layer 23, the protective film 8 a, and the like. The insulating layer 3 may be made of a suitable insulating ceramic such as SiO₂, SiN, Ta₂O₅, or AlN. Alternatively, an insulating material such as glass or resin may be used.

Thereafter, as illustrated in FIG. 14( a), the insulating layer 3 is abraded to flatten its upper surface.

Next, as illustrated in FIG. 14( b), the support substrate 2 is laminated on top of the insulating layer 3 that has been flattened.

Next, the temporary joining layer 21 mentioned above is removed by etching, and separated from the piezoelectric thin plate 5. Consequently, the piezoelectric thin plate 5 can be detached from the temporary support member 22. In this way, as illustrated in FIG. 14( c), a structure is obtained in which the dummy layer 23, the second electrode 7, and the piezoelectric thin plate 5 are laminated over the lower surface of the support substrate 2 via the insulating layer 3. Next, as illustrated in FIG. 15( a), this structure is turned upside down, and the first electrode 6 and the line electrode 9 are formed on the piezoelectric thin plate 5 by photolithography.

Thereafter, the slits 5 a and 5 b, and a via-hole-forming electrode hole are formed in the piezoelectric thin plate 5 by etching. Next, as illustrated in FIG. 15( b), the via-hole electrode 11 is formed.

Thereafter, the dummy layer 23 is removed by etching. In this way, the state illustrated in FIG. 15( c) is obtained, in which the recess 3 a is formed, and the piezoelectric thin plate vibrating part 4 is made afloat. Lastly, as illustrated in FIG. 1( a), the bumps 12 and 10 are formed on the via-hole electrode 11 and the line electrode 9, respectively. In this way, the piezoelectric bulk wave device 1 according to the embodiment mentioned above can be provided. According to the above-mentioned manufacturing method, ions are implanted into the piezoelectric substrate 5A having a large thickness in advance. Consequently, the piezoelectric substrate 5A can be easily split at the high concentration ion-implanted portion 5 x to thereby obtain the piezoelectric thin plate 5. According to this method, the piezoelectric thin plate 5 with a relatively small thickness can be obtained with high accuracy.

While the piezoelectric bulk wave device according to the present invention can be manufactured by the manufacturing method according to the above-mentioned embodiment, the piezoelectric bulk wave device may be manufactured by other methods.

For example, in the above-mentioned embodiment, the piezoelectric thin plate and the remaining piezoelectric substrate portion are separated from each other after bonding the temporary support member 22 onto one side of the piezoelectric substrate. However, the step of preparing the piezoelectric thin plate may be performed as follows. That is, the piezoelectric thin plate may be prepared by performing the steps of implanting ions from one side of the piezoelectric substrate made of LiTaO₃ to form the high concentration ion-implanted potion mentioned above, joining the support substrate to the one side of the piezoelectric substrate, and then separating the piezoelectric substrate at the high concentration ion-implanted portion while heating the piezoelectric substrate, into a piezoelectric thin plate that extends from the one side of the piezoelectric substrate to the high concentration ion-implanted portion, and the remaining substrate portion. More specifically, the piezoelectric substrate 5A having the high concentration ion-implanted portion 5 x as illustrated in FIG. 12( a) is prepared by ion implantation. Next, the first electrode is formed on the side of the piezoelectric substrate 5A from which ions have been implanted. Thereafter, the support substrate 2 is joined to the side of the piezoelectric substrate 5A from which ions have been implanted, that is, the side of the piezoelectric substrate 5A on which the first electrode is formed. In that state, while heating the piezoelectric substrate 5A, the piezoelectric substrate 5A is separated into the piezoelectric thin plate and the remaining piezoelectric substrate portion in the same manner as in the embodiment mentioned above. Next, the second electrode may be formed on the side of the piezoelectric thin plate opposite to the side on which the first electrode is formed.

Other than by implanting ions into the piezoelectric substrate made of LiTaO₃ and splitting the piezoelectric substrate, the formation of the piezoelectric thin plate may be achieved by abrasion of the piezoelectric substrate, etching of the piezoelectric substrate, or the like.

The above-mentioned piezoelectric bulk wave device 1 is merely an example of piezoelectric bulk wave device according to the present invention. The characteristic feature of the present invention resides in setting the Euler Angles of LiTaO₃ to a specific range to effectively utilize resonance characteristics according to thickness shear vibration mode. Therefore, the material, shape, and the like of the first and second electrodes are not particularly limited. Moreover, the piezoelectric bulk wave device may be configured so as to have an electrode structure that functions not only as a resonator but also as various band-pass filters.

REFERENCE SIGNS LIST

-   -   1 piezoelectric bulk wave device     -   2 support substrate     -   3 insulating layer     -   3 a recess     -   4 piezoelectric thin plate vibrating part     -   5 piezoelectric thin plate     -   5A piezoelectric substrate     -   5 a, 5 b slit     -   5 x high concentration ion-implanted portion     -   6 first electrode     -   7 second electrode     -   8 line electrode     -   8 a protective film     -   9 line electrode     -   10 bump     -   11 via-hole electrode     -   12 bump     -   21 temporary joining layer     -   22 temporary support member     -   23 dummy layer 

1. A piezoelectric bulk wave device comprising: a piezoelectric plate made of LiTaO₃; and first and second electrodes provided in contact with the piezoelectric plate, wherein the piezoelectric bulk wave device is configured to utilize a thickness shear mode of the piezoelectric thin plate made of LiTaO₃, and wherein of Euler Angles (φ, θ, φ) of the LiTaO₃, φ is 0°, and θ is in a range of not less than 54° and not more than 107°.
 2. The piezoelectric bulk wave device according to claim 1, wherein the θ of the Euler Angles of the LiTaO₃ is in a range of 55° to 88°.
 3. The piezoelectric bulk wave device according to claim 1, wherein the θ of the Euler Angles of the LiTaO₃ is in a range of 62° to 87°.
 4. The piezoelectric bulk wave device according to claim 1, further comprising: a support substrate; and an insulating layer on the support substrate, the insulating layer defining a recess, the piezoelectric plate being disposed above the recess.
 5. The piezoelectric bulk wave device according to claim 1, wherein the piezoelectric plate is a monocrystal piezoelectric body with a thickness of not more than 2 μm.
 6. A method of manufacturing a piezoelectric bulk wave device, the piezoelectric bulk wave device utilizing a thickness shear mode of a piezoelectric plate made of LiTaO₃, the method comprising: preparing a piezoelectric plate having Euler Angles (φ, θ, φ), of which φ is 0°, and θ is in a range of not less than 54° and not more than 107°; forming a first electrode in contact with the piezoelectric plate; and forming a second electrode in contact with the piezoelectric plate.
 7. The method of manufacturing a piezoelectric bulk wave device according to claim 6, wherein the step of preparing the piezoelectric thin plate includes: implanting ions from a first side of a piezoelectric substrate made of LiTaO₃ to form a high concentration ion-implanted portion on the one side, the high concentration ion-implanted portion being a portion of highest implanted-ion concentration; joining a support substrate to the first side of the piezoelectric substrate; and separating the piezoelectric substrate at the high concentration ion-implanted portion, while heating the piezoelectric substrate, into the piezoelectric plate that extends from the first side of the piezoelectric substrate to the high concentration ion-implanted portion and a second piezoelectric substrate portion.
 8. The method of manufacturing a piezoelectric bulk wave device according to claim 6, wherein: the step of preparing the piezoelectric thin plate includes the steps of implanting ions from a first side of a piezoelectric substrate made of LiTaO₃ to form a high concentration ion-implanted portion on the first side, the high concentration ion-implanted portion being a portion of highest implanted-ion concentration, bonding a temporary support member onto the first side of the piezoelectric substrate, and separating the piezoelectric substrate at the high concentration ion-implanted portion, while heating the piezoelectric substrate bonded on the temporary support member, into the piezoelectric plate that extends from the first side of the piezoelectric substrate to the high concentration ion-implanted portion, and a remaining piezoelectric substrate portion; and detaching the temporary support member from the piezoelectric plate.
 9. The method of manufacturing a piezoelectric bulk wave device according to claim 8, wherein: prior to detaching the temporary support member from the piezoelectric plate, the steps of forming a first electrode on the piezoelectric plate, forming a dummy layer to cover the first electrode, and laminating a support substrate on the dummy layer are performed; and after detaching the temporary support member from the piezoelectric plate, forming a second electrode on a second side of the piezoelectric plate which is exposed by the detaching of the temporary support member, and causing the dummy layer to disappear.
 10. The method of manufacturing a piezoelectric bulk wave device according to claim 6, wherein the θ of the Euler Angles of the LiTaO₃ is in a range of 55° to 88°.
 11. The method of manufacturing a piezoelectric bulk wave device according to claim 6, wherein the θ of the Euler Angles of the LiTaO₃ is in a range of 62° to 87°.
 12. The method of manufacturing a piezoelectric bulk wave device according to claim 6, wherein the piezoelectric plate is a monocrystal piezoelectric body with a thickness of not more than 2 μm. 